UiO-67 is a Zirconium-based metal-organic framework that features larger pore sizes compared to UiO-66.  This is due to the longer structure of BPDC (UiO-67) as compared to BDC (UiO-66).

Application

  • Gas adsorption and storage:
    • Carbon dioxide (CO2)
    • Hydrogen (H2)
    • Methane (CH4)
  • Neutralisation/detoxication of chemical warfare agents (nerve gas)
  • Catalyst
  • Biomolecular motor
  • Biomedical imaging

Properties

Formula:            Zr6O4(OH)4(BPDC)6

Surface area:     up to 1970+ m2/gr (BET)

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UiO-67 metal-organic framework

Publications

Incorporation of Functional Groups Expands the Applications of UiO‐67 for Adsorption, Catalysis and Thiols Detection

Tailoring the Pore Size and Functionality of UiO-Type Metal–Organic Frameworks for Optimal Nerve Agent Destruction

H2 Storage in isostructural UiO-67 and UiO-66 MOFs

A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability

UiO-67-type Metal–Organic Frameworks with Enhanced Water Stability and Methane Adsorption Capacity

Preparation, characterization, and performance evaluation of UiO-66 analogues as stationary phase in HPLC for the separation of substituted benzenes and polycyclic aromatic hydrocarbons

A facile synthesis of UiO-66, UiO-67 and their derivatives